1-(4-Fluorobenzyl)-2-(pyridin-2-yl)-1H-benzimidazole

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1-(4-Fluoro­benz­yl)-2-(pyridin-2-yl)-1H-benzimidazole

In the title compound, C19H14FN3, the dihedral angles between the benzimidazole unit (r.m.s. deviation= 0.017 Å) and the pyridine and benzene rings are 24.46 (4) and 81.87 (3)°, respectively. In the crystal, mol-ecules are stacked along the a-axis direction by C-H⋯π inter-actions.

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2-(Pyridin-4-yl)-1H-benzimidazole

The title compound, C12H9N3, is an unhydrated analogue of the previously reported trihydrate. The mol-ecule is essentially planar, with a 3.62 (11)° angle between the pyridine and benzimidazole planes. In the crystal, N-H⋯N hydrogen bonds result in chains of mol-ecules parallel to [010], which are additionally linked by weak π-π stacking inter-actions [centroid-centroid distance = 3.7469 (17) Å...

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Glutaric acid–2-(pyridin-4-yl)-1H-benzimidazole (1/1)

The crystal structure of the title co-crystal, C(12)H(9)N(3)·C(5)H(8)O(4), N-H⋯O and O-H⋯N hydrogen bonds link the components. There are also π-π stacking inter-actions between the imidazole rings, between the imidazole and pyridine rings and between the pyridine and benzene rings [centroid-centroid distances = 3.643 (2), 3.573 (2) and 3.740 (1)Å, respectively].

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1-(2,3,4,5,6-Penta­methyl­benz­yl)-2-(pyridin-2-yl)-1H-benzimidazole

In the title compound, C24H25N3, the benzimidazole ring system is essentially planar, with an r.m.s. deviation of 0.017 Å, and forms dihedral angles of 7.81 (5) and 87.61 (4)° with the pyridine and benzene rings, respectively. An intra-molecular C-H⋯N hydrogen bond is observed. In the crystal, mol-ecules are stacked along the a axis by weak C-H⋯π inter-actions.

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1-(4-Methyl­phenyl­sulfon­yl)-2-{[3-methyl-4-(2,2,2-tri­fluoro­eth­oxy)pyridin-2-yl]methyl­sulfan­yl}-1H-1,3-benzimidazole

In the title compound, C23H20F3N3O3S2, the benzo-imidazole unit makes dihedral angles of 5.02 (1) and 76.42 (1)°, respectively, with the pyridine and methyl-benzene rings; the dihedral angle between the pyridine and methyl-benzene rings is 72.19 (1)°. In the crystal, mol-ecules are connected by weak C-H⋯F, C-H⋯O and C-H⋯N hydrogen bonds. Weak C-H⋯π inter-actions and π-π stacking [centroid-centr...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2014

ISSN: 1600-5368

DOI: 10.1107/s1600536814005947